Uncertainty of measurement: emissivity of a reflective foil

Reflective foil laminates are used in thermal insulation of buildings. A standard test method [SANS 1381-4] describes the measurement (amongst other properties) of their emissivity using a thermopile radiation thermometer. This article describes how to estimate the uncertainty of measurement (UoM) in this application of infrared radiation thermometry.

The documentary standard SANS 1381-4 requires that the emissivity of one reflective surface of the specimen being tested be less than or equal to 0.05, or 5% (clause 4.8).
To measure the emissivity (clause 5.8), half of the specimen’s surface is painted black, the specimen is heated to 70 °C (presumably, this temperature is chosen to represent a typical situation in use, in a ceiling or around a hot water geyser), and the total amounts of thermal radiation coming from the reflective part and from the blackened part are measured by a calibrated thermopile (clause The emissivity of the blackened part, Latex formula, is assumed to be 0.95, or 95% (clause The thermopile output signals when viewing the reflective part, Latex formula, and the blackened part, Latex formula, are used to calculate the emissivity of the reflective part, Latex formula, as follows: Latex formula, or Latex formula (clause 5.8.4).

To understand the relationship between thermopile output, target emissivity and temperature, let’s analyse the heat transfer to and from the detector surface (thermopile hot junction):

Let the target (foil) temperature be Latex formula (70 °C, in this case), ambient temperature be Latex formula (probably 23 °C), thermopile hot junction temperature be Latex formula and thermopile cold junction temperature be Latex formula.

The voltage output of the thermopile, Latex formula, is proportional to the difference between hot and cold junction temperatures, that is, Latex formula.

We express the total amounts of thermal radiation using the Stefan-Boltzmann law. The nett thermal radiation entering the detector is the sum of that emitted by the target to the thermopile hot junction, Latex formula, plus that reflected by the target from the surroundings to the hot junction, Latex formula, minus that emitted from the hot junction, Latex formula.

Heat transferred by convection from the thermopile hot junction to the adjacent air is Latex formula, where Latex formula is the convection heat transfer coefficient and Latex formula is the surface area of the hot junction or detector.

This is all the heat transferred from the outside world to the detector surface (hot junction). At equilibrium, it is balanced by heat transferred from the hot junction towards the cold junction (within the body of the detector) by conduction. This heat flow causes a temperature gradient between hot and cold junctions, with the thermal conductivity of the detector body, Latex formula, relating the temperature difference to the amount of heat flowing: Latex formula, where Latex formula is the distance between hot and cold junctions.

At equilibrium, the heat transferred to the detector surface by radiation and convection should be equal to that lost to the cold junction side by conduction: Latex formula.

Rearranging the above equation, Latex formula.

Let us assume that the thermopile backside has an efficient heatsink, so that Latex formula. (Deviations from ideal behaviour, for example, due to changes in the thermopile cold junction temperature with increasing incident radiation, should be evident from the thermopile’s calibration results.) Then, the equation becomes Latex formula.

At this point, I get stuck: I would hope to reduce this to Latex formula or, equivalently, Latex formula, so that thermopile output Latex formula is proportional to Latex formula.

Returning to the simple equation Latex formula used in SANS 1381-4, let’s identify the sources of uncertainty:

The dependence of the thermopile output Latex formula on target temperature Latex formula and ambient temperature Latex formula is shown on the right-hand side of the equation derived above. As Latex formula and Latex formula are functions of Latex formula and Latex formula, any variation in these temperatures will cause variation in the signals Latex formula and Latex formula. The ratio Latex formula does not depend on the values of Latex formula and Latex formula, as these terms are the same in numerator and denominator and cancel out, but only on their stability during the time required to measure Latex formula and Latex formula. For this reason, we do not explicitly include uncertainties in these temperatures, but rely on them being captured in the standard deviations of Latex formula and Latex formula.

The uncertainty in thermopile output signals introduced by the digital multimeter (DMM) used to measure them is typically around Latex formula of the measured signal (for a 6.5-digit DMM). This is negligible, compared to the repeatability components (experimental standard deviation of the mean, or ESDM) and uncertainty in the emissivity of the blackened part of the specimen. For this reason, we do not consider uncertainties arising from the DMM any further.

The distance between the thermopile detector and the target (reflective part or blackened part of the specimen) should not affect the results, provided that the target always fills the field-of-view of the detector. So, as long as the detector is close enough to the specimen, no uncertainty results from slight variation in this distance.

The standard deviations (ESDM, to be precise) of Latex formula and Latex formula must be taken into account. As Latex formula is typically a very small value, its ESDM is particularly significant (see numerical example, below).

The relative uncertainty in Latex formula is roughly estimated to be Latex formula. (In other words, Latex formula.) If this component appears to be significant in the following numerical example, we will try to estimate it more precisely.

Numerical example:

Measurements of Latex formula: 1 μV, 8 μV, 0 μV, 11 μV, 6 μV and 9 μV. (Mean = Latex formula, standard deviation = Latex formula, ESDM = Latex formula, relative uncertainty Latex formula.)

Measurements of Latex formula: 424 μV, 411 μV, 410 μV, 417 μV, 378 μV and 378 μV. (Mean = Latex formula, standard deviation = Latex formula, ESDM = Latex formula, relative uncertainty Latex formula.)

Result for emissivity: Latex formula, or 1.4%.

As the relation between Latex formula and Latex formula, Latex formula and Latex formula is one of simple multiplication and division, we can combine the relative uncertainties simply:

Latex formula.

The effective degrees of freedom, Latex formula, will be close to those of the dominant component, Latex formula: Latex formula, since Latex formula readings were taken. For Latex formula, the coverage factor for a level of confidence of 95.45% is 2.65. So, the expanded relative uncertainty is Latex formula, the expanded absolute uncertainty is Latex formula and the measurement result is Latex formula, or Latex formula.

Take care! When the quantity being measured (emissivity, in this case) is dimensionless and expressed in percent, and its relative uncertainty is expressed in percent, confusion can arise. The expanded relative uncertainty estimated above is 0.8, or 80%, of the measured value. It is not already an absolute uncertainty in emissivity, in other words, the result is not Latex formula, which would be nonsensical.

We see that Latex formula is the dominant component of uncertainty, by far. As Latex formula is unlikely to be significant compared to this, it is not necessary to estimate the latter component more precisely than the rough estimate we used earlier.

Note, regarding the simple combination of relative uncertainties performed above: This is only correct when the function is one of simple multiplication and division. For more general situations, the sensitivity coefficient must be determined by taking the partial derivative. The equivalence of these approaches for the simple equation Latex formula is demonstrated below:

Latex formula Latex formula.

(Contact the author at lmc-solutions.co.za.)

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